Database Survey of Single-and-Half Phosphorus–Oxygen Bonds in Salts with the C2PO2 Segment: Crystal Structure of [NH2C5H4NH][(C6H5)2P(O)(O)]⋅2H2O

Crystallography Reports - For structures with a C2PO2 skeleton, a comparison of “single-and-half” phosphorus–oxygen bonds with single and double phosphorus–oxygen bonds is...     

Nonlinear axisymmetric thermomechanical response of piezo-FGM shallow spherical shells

Thermomechanical instability of shallow spherical shells made of functionally graded material (FGM) and surface-bonded piezoelectric actuators is studied in this paper. The governing equations are based on the classical shell theory of shells and the Sanders nonlinear kinematics equations. It is assumed that the property of the FGMs varies continuously through the thickness of the shell according to a power law distribution of the volume fraction of the constituent materials. The constituent materials of the functionally graded shell are assumed to be mixture of ceramic and metal. The analytical solutions are obtained for uniform external pressure, thermal loading, and constant applied actuator voltage.     

Optical solitons and optical rogons of generalized resonant dispersive nonlinear Schrödinger's equation with power law nonlinearity

This paper obtains solitons and singular periodic solutions to the generalized resonant dispersive nonlinear Schrödinger’ equation with power law nonlinearity. There are several integration tools that are adopted to extract these solutions. They are simplest equation method, functional variable method, sine–cosine function method, tanh function method and the G′/G-expansion method. These integration techniques reveal bright and singular solitons as well as the corresponding singular periodic solutions to the nonlinear evolution equation. These solitons solutions are important in the nonlinear fiber optics community as well as in the study of rogue waves.     

Effect of second monomer and initiator type, mixing method, and stabilizer content on the shape of the particles produced by seeded dispersion polymerization in the presence of saturated hydrocarbon droplets

In this work, the preparation of micron-sized polymer particles with nonspherical shapes via seeded dispersion polymerization of 2-ethylhexyl methacrylate with polystyrene seed particles in the presence of hydrocarbon droplets and evaporation of hydrocarbon after the polymerization under various polymerization conditions was discussed. The effect of second monomer and initiator type, mixing method, and stabilizer content on the shape of the obtained particles was investigated. It was observed that particles with more nonspherical shapes were obtained with increasing the alkyl chain length of ester group of the methacrylate of the second monomer which is because of increasing the absorption amounts of hydrocarbon by second polymer domains. Moreover, the experimental results showed that shape of the particles which was produced by shaking is more nonspherical than the shape of the particles which was obtained from tumbling. Furthermore, particles with different nonspherical shapes were prepared by changing the initiator type and stabilizer content.     

Direct synthesis of Zn(II) and Cu(II) coordination polymers based on 4,4′-bipyridine and 1,10-phenanthroline and evaluating their effects as catalyst on ammonium perchlorate thermal decomposition

Journal of Thermal Analysis and Calorimetry - Two coordination polymers (CPs) material, [Zn(μ-Cl)2(μ-bpy)]∞ (bpy?=?4,4′-bipyridine) and [Cu(bpy)(phen)(ClO4)2]n...     

Classification of designs with nontrivial automorphism groups

In this article, we introduce a new orderly backtrack algorithm with efficient isomorph rejection for classification of t‐designs. As an application, we classify all simple 2‐(13,3,2) designs with nontrivial automorphism groups. The total number of such designs amounts to 1,897,386. The decomposability of the designs is also considered. © 2005 Wiley Periodicals, Inc. J Combin Designs 14: 479–489, 2006     

Improving of Anticancer Activity and Solubility of Cisplatin by Methylglycine and Methyl Amine Ligands Against Human Breast Adenocarcinoma Cell Line

Methylglycine, also known sarcosine, is dramatically used in drug molecules and its metal complexes can interact to DNA and also do cleavage. Hence, to study the influence of methylglycine ligand on biological behavior of metal complexes, two water-soluble platinum (II) complexes with the formula cis-[Pt(NH₃)₂(CH₃-gly)]NO₃ and cis-[Pt(NH₂-CH₃)₂(CH₃-gly)]NO₃ (where CH₃-gly is methylglycine) have been synthesized and characterized by spectroscopic methods, molar conductivity measurements, and elemental analyzes. The anticancer activity of synthesized complexes was tested against human breast adenocarcinoma cell line of MCF7 using MTT assay and results showed excellent anticancer activity with Cc₅₀ values of 126 and 292 μM after 24 h incubation time, for both complexes of cis-[Pt(NH₃)₂(CH₃gly)]NO₃ and cis-[Pt(NH₂-CH₃)₂(CH₃gly)]NO₃, respectively. Also, the interaction between Pt(II) complexes with calf thymus DNA was extensively studied by means of absorption spectroscopy, fluorescence titration spectra displacement with ethidium bromide (EtBr), and circular dichroism studied in Tris-buffer. The obtained spectroscopic results revealed that two complexes can bind to highly polymerized calf thymus DNA cooperatively and denature at micromolar concentrations. The fluorescence data indicate that quenching effect for cis-[Pt(NH₃)₂(CH₃gly)]NO₃ (K_sv?=?9.48 mM^?1) was higher than that of cis-[Pt(NH₂-CH₃)₂(CH₃gly)]NO₃ (K_sv?= 1.98 mM^?1). These results were also confirmed by circular dichrosim spectra. Consequently, docking data showed that cis-[Pt(NH₃)₂(CH₃gly)]NO₃ with more interaction energy binds on DNA via groove binding which is more compatible with experimental results.

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Graphical Abstract ? Two anticancer Pt(II) complexes, cis-[Pt(NH₃)₂(CH₃gly)]NO₃ and cis-[Pt(NH_2?CH₃)₂(CH₃gly)]NO₃, have been synthesized and interacted with calf thymus DNA. Improving solubility of these compounds reduce side effects and increase anticancer activity against human breast cell line. Modes of binding have been studied by electronic absorption, fluorescence, and CD measurements. Results show that both Pt(II) complexes can interact to DNA via groove binding.

     

Equilibrium and kinetic study of novel methyltrimethoxysilane magnetic titanium dioxide nanocomposite for methylene blue adsorption from aqueous media

Novel magnetic titanium dioxide nanoparticles decorated with methyltrimethoxysilane (Fe₃O₄@TiO₂‐MTMOS) were successfully fabricated via a sol–gel method at room temperature. The synthesized material was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, thermogravimetric analysis and vibrating sample magnetometry. The removal efficiency of the adsorbent was evaluated through the adsorption of methylene blue (MB) dye from water samples. The adsorption isotherm and kinetics were evaluated using various models. The Langmuir model indicated a high adsorption capacity (11.5 mg g^?1) of Fe₃O₄@TiO₂‐MTMOS. The nanocomposite exhibited high removal efficiency (96%) and good regeneration (10 times) compared to Fe₃O₄ and Fe₃O₄@TiO₂ at pH = 9.0. Based on the adsorption mechanism, electrostatic interaction plays a main role in adsorption since MB dye is cationic in nature at pH = 9, whereas the adsorbent acquired an anionic nature. The newly synthesized Fe₃O₄@TiO₂‐MTMOS can be used as a promising material for efficient removal of MB dye from aqueous media.     

Simultaneous Investigation of the Laser Intensity and Magnetic Field Effects on Laser-Induced Plasma Spectroscopy

Journal of Russian Laser Research - In this paper, we use laser-induced breakdown spectroscopy (LIBS) to investigate the laser-induced copper plasma with and without an external magnetic field,...     

Dispersive dark optical soliton with Schödinger-Hirota equation by G′/G-expansion approach in power law medium

This paper studies dispersive optical solitons that are governed by the Schrödinger-Hirota equation with power law nonlinearity. The G′/G-expansion method is applied to extract soliton solution to this equation. This approach reveals dark 1-soliton solution to the equation.